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Silicon Nitride (Si3N4) Ceramics

Silicon nitride (Si₃N₄) is a covalent compound with high hardness, wear resistance, thermal stability, and chemical stability. It can withstand high temperatures, with a decomposition temperature of about 1900°C and a practical usage temperature up to 1400°C. It has excellent mechanical strength, with a bending strength exceeding 980 MPa, and can endure high-temperature thermal shock without cracking. Silicon nitride is highly resistant to most inorganic acids, many organic substances, and molten non-ferrous metals, and also exhibits excellent electrical insulation and optical transparency.

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Silicon Nitride Ceramic Application

At GESmaterials, we supply Silicon Nitride (Si₃N₄), a high-performance ceramic known for its superior mechanical strength, low density, and excellent resistance to wear, corrosion, and thermal shock. Its unique characteristics make it indispensable in advanced engineering applications:

Precision Bearings
Si₃N₄ bearing balls are widely used in automobiles, aerospace systems, high-speed engines, and performance racing vehicles. Compared with steel bearings, ceramic bearings offer higher strength at elevated temperatures, lower friction, longer service life, and the ability to resist corrosive environments.

High-Temperature Components
Si₃N₄ is one of the few monolithic ceramics capable of withstanding severe thermal shock and steep temperature gradients. It has been evaluated and applied in demanding environments such as hydrogen-oxygen rocket engines, where extreme conditions quickly degrade conventional materials.

Corrosion-Resistant Engineering
Thanks to its chemical inertness, silicon nitride performs reliably in harsh environments where metals and other ceramics fail. It is increasingly used in industrial machinery, chemical processing equipment, and marine applications requiring long-term durability.

Silicon Nitride Ceramics

Properties
Chemical FormulaSi3N4
Mechanical
Density3.26 g/cm3
Hardness14 GPa
Modulus of Elasticity300 GPa
Flexural Strength800 MPa
Compressive Strength3000 MPa
Poisson’s Ratio0.28
Fracture Toughness7 MPa m½
Electrical
Dielectric Strength13 ac V/mm
Dielectric Constant9.6 (@ 1 MHz)
Volume Resistivity10^14 ohm-cm
Thermal
Coefficient of Thermal Expansion3.1 x 10^-6/°C
Thermal Conductivity17 W/(m*K)
Specific Heat0.65 x10^3 J/(Kg*K)
Shock Resistance800 °C Diff.
Maximum Working Temperature1300 °C

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